I've been reading a story where the (primitive) extraction of mercury from cinnabar plays an important role. I knew next to nothing about cinnabar (other than it is an ore, and maybe that it was red), so off to the internet I went.
I've spend a couple of hours over the last few weeks reading this stuff. I eventually shifted from cinnabar and mercury, to why steel making has been known for so long, and yet didn't become common until the latter half of the 19th century.
The first bits of trivia come from the site History of Metals. It never really occurred to me, but most metals were not known until the last few centuries. The reason was the inability to get enough energy into the ore to get the metal to separate out. For example, the alloy bronze (copper and tin) is ancient because both metals can be obtained at wood fire temperatures, but brass is only 225 years old because zinc is substituted for tin, and wasn't available before the 17th century.
Then there is the story of iron and steel. I didn't know that iron is almost never found in an easy to use form (mostly from meteorites) and was considered a precious metal at times. Later, they figured out how to obtain it by smelting. The problem was that it was strong, but somewhat brittle.
Steel is an iron alloy that is much less brittle (that much I knew). I didn't know that the big deal with steel up to about 500 years ago was that a steel sword could be much longer than an iron one because it was less brittle. Now that makes a lot of sense.
But, what's the big deal about making steel? I knew they had trouble making it, and that this had something to do with impurities, but that was the end of it. These related sites (History of Steel, and Damascene Technique in Metal Working) are written from a detective work perspective, and are fairly accessible to the novice.
So, here's the deal. You melt some ore and extract some fairly pure iron. This comes out in small chunks called blooms. So, what do you do with it? The impurities are important. If it has a lot of carbon in it you get iron for casting: it melts at a low temperature so you can pour it, but it is too brittle for weapons. If it is low in carbon you get wrought iron, which is far less brittle, but tougher to work with.
In the old days the way that you made steel was that you cleaned up the impurities in wrought iron. To do this, you heat up the iron and beat the impurities out (or break them up into smaller pieces). Even better, you can beat it really flat, and then either stack multiple pieces, twist multiple pieces, or fold over the one piece, and beat repeatedly. I always understood that the beating helped to shape the metal, but no one ever made it clear that this was what strengthened it too (neither did my 6th grade metal shop teacher who had no clue why I broke two shafts for my screwdriver project). This is where the idea of Damascus steel and Damascene methods comes in - its the beating of the wrought iron that makes it into steel.
There is also the effect of cooling and heating the wrought iron. Cooling it properly gets the chemistry right to make wrought iron into steel. Heating it (with charcoal or coke) is what increases the concentration of the carbon that imparts strength (but you can't use coal which is loaded with different impurities).
And where does the Bessemer process come in? We all learn in history that this was important, but what was the big deal? Bessemer came up with the idea that rather than heating good impurities into and beating bad impurities out of wrought iron, you could instead start with the already carbon rich (and cheap) cast iron. Melt it down and blow air through it (thus, the blast furnace) to get the excess carbon out. And here's the neat trick: blowing the air through it keeps it hot (because of chemical reactions), and you can even gage the amount of impurities left in the steel by the temperature you get the molten steel too. I thought that was pretty cool.
Now ... if only this would come up in a fashionable circle so that I could use all this as a conversational gambit.